Product ID:BLACK MARKING INK #7274
MSDS Date:03/10/1986
FSC:7510
NIIN:00-469-7910
Status Code:A
MSDS Number: CLBCB

CROWN INDUSTRIAL PRODUCTS, CO.

STATE LINE ROAD
HEBRON, IL 60034

Emergency Phone: 815-338-2141

Info Phone: 815-648-2424/815-338-2141(NIGHT)

Preparer: ROBERTE. BAYTON

Cage: DO171

CROWN INDUSTRIAL PRODUCTS, CO.

HEBRON, IL 60034

Telephone: 815-648-2424/815-338-2141(NIGHT)

Cage: DO171

METHYL ETHYL KETONE

CAS: 78-93-3

RTECS: EL6475000

OSHA PEL 200 PPM

ACGIH TLV: 200 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

METHYLENE CHLORIDE

CAS: 75-09-2

RTECS: PA8050000

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

PETROLEUM GASES, LIQUEFIED, SWEETENED

CAS: 68476-86-8

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

Health Hazards Acute and Chronic:INHALATION: HIGH VAPOR CONCENTRATIONS
MAY RESULT IN DIZZINESS, HEADACHES AND UNCONSCIOUSNESS. INGESTION:
NOT LIKELY. EYE CONTACT: EYE IRRITATANT. CAN CAUSE CORNEAL DAMAGE.
SKIN CONTACT: PROLONGED CONT ACT WILL CAUSE DEFATTING OF THE SKIN
LEADING TO IRRITATION AND DERMITIS. SKIN ABSORBTION: NOT LIKELY IN
TOXIC AMOUNTS.
Medical Cond Aggravated by Exposure:

First Aid:OBTAIN MEDICAL ATTENTION IN ALL CASES. EYES: FLUSH WITH WATER
FOR 15 MINITUES OR UNTIL IRRITATION SUBSIDES. SKIN: REMOVE ALL
CONTAMINATED CLOTHING; WASH SKIN WITH SOAP AND WATER. INHALATION:
REMOVE FR OM EXPOSURE IMMEDIATELY. IF BREATHING IS IRREGULAR OR
STOPPED, BEGIN ARTIFICIAL RESPIRATION AND ADMINISTER OXYGEN.
INGESTION: DRINK LARGE AMOUNTS OF WATER AND INDUCE VOMITING. TARGET
ORGAN AFFECTED: R ESPIRATORY TRACT IRRITATION. CAN CAUSE NERVOUS
SYSTEM DEPREEION IN HIGH CONCENTRATIONS. MAY CAUSE LIVER AND KIDNEY
DAMAGE.

Flash Point Method:TCC
Flash Point:<-6.5C, 20.F
20F
Lower Limits:1.8
Upper Limits:9.5
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM
Unusual Fire/Explosion Hazard:TREAT AS CYLINDERS OF COMPRESSES GAS.

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION. AVOID
BREATHING VAPORS. REMOVE ALL INERT MATERIALS AND NON-SPARKING
TOOLS.

Handling and Storage Precautions:DO NOT STORE IN DIRECT SUNLIGHT, NEAR
OPEN FLAMES OR RADIATORS, OR AT TEMPATURES EXCEEDING 120 F.

Respiratory Protection:REPIRATORY PROTECTION PROGRAM SHOULD BE IN
ACCORDANCE WITH 29 CFR 1910.134.
Ventilation:LOCAL EXHAUST IS ADEQUATE.
Protective Gloves:POLYETHYLENE OR NEOPRENE
Eye Protection:SAFTEY GLASSES
Other Protective Equipment:PROTECTIVE CLOTHING AND EQUIPMENT: SEE 29
CFR 1910.132 AND 133
Work Hygienic Practices:WASH SKIN WITH SOAP AND WATER
Supplemental Safety and Health

Vapor Pres:45-50 PSIG @ 70 F
Vapor Density:>1
Spec Gravity:<1
Evaporation Rate & Reference:ETHER=1 <1
Solubility in Water:NEG.
Appearance and Odor:BLACK KETONE LIKE ODOR
Percent Volatiles by Volume:>90%

Stability Indicator/Materials to Avoid:YES
AVOID ALKALINE MATERIALS AND MINERAL ACIDS.
Stability Condition to Avoid:OPEN FLAMES OR ELECTRICAL ARCS.
Hazardous Decomposition Products:BURNING CAN PRODUCE CARBON MONOXIDE
AND/OR CARBON DIOXIDE.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.